Author: Thomas Sören Hoffmann. Translated by Pedro Sepúlveda Zambrano.

Roald Hoffmann's contributions to chemistry are well known; this Nobel laureate has published more than 500 articles and two books. As an "applied theoretical chemist," he has made significant contributions to our understanding of chemical bonding and reactivity, and taught two generations of chemists how to use molecular orbitals for real chemistry. Less well known, however, are Hoffmann's important and insightful contributions to the areas of scholarship surrounding chemistry. Over a career that spans nearly fifty years, Roald (...) class='Hi'>Hoffmann has thought and written copiously about the broader context of chemistry and its relationship to the arts and poetry. This book contains Hoffmann's essays and is organized around several major themes: chemical reasoning and explanation, writing and communicating in science, ethics, art and science, and chemical education. A few are unpublished lectures that are valuable additions to the volume. The editors have the full cooperation of Roald Hoffmann in this project. Most of the published work will be reprinted verbatim, but a few of the essays will be revised to eliminate redundancy. The unpublished lectures will also be edited since they were originally intended to be delivered orally at specific occasions. The editors will provide an introduction to the book, and some introductory material for each section. In introducing the material, they will highlight the intrinsic importance and interest of the ideas, as well as the places where Hoffmann's thought makes novel contributions to cognate areas. (shrink)

Abductive reasoning takes place in forming``hypotheses'''' in order to explain ``facts.'''' Thus, theconcept of abduction promises an understanding ofcreativity in science and learning. It raises,however, also a lot of problems. Some of them will bediscussed in this paper. After analyzing thedifference between induction and abduction (1), Ishall discuss Peirce''s claim that there is a ``logic''''of abduction (2). The thesis is that this claim can beunderstood, if we make a clear distinction between inferential elements and perceptive elements of abductive reasoning. For (...) Peirce, the creative act offorming explanatory hypotheses and the emergence of``new ideas'''' belongs exclusively to the perceptive side of abduction. Thus, it is necessary to study the roleof perception in abductive reasoning (3). A furtherproblem is the question whether there is arelationship between abduction and Peirce''s concept of``theorematic reasoning'''' in mathematics (4). Both forms of reasoning could be connected, because both arebased on perception. The last problem concerns therole of instincts in explaining the success ofabductive reasoning in science, and the question whether the concept of instinct might be replaced bymethods of inquiry (5). (shrink)

No limiar do Terceiro Milênio do cristianismo, defrontamo-nos com novos paradigmas tanto na organização do mundo do trabalho, como nos demais espaços sociais, com repercussões bem acentuadas no campo religioso e que impõem novas demandas à formação da freira. Pretende-se, nesse estudo, fundamentar a necessidade e as possibilidades de articulação entre os elementos básicos que constituem a formação para a cidadania e competência da freira enquanto mulher e cidadã, através das ações desenvolvidas por congregações religiosas femininas.

O presente estudo faz uma análise da institucionalização da formação da mulher das camadas populares de Porto Alegre, no século XIX. Em decorrência da transformação social, econômica e política, tornou-se necessário um empenho sistematizado para inserir a menina órfã na sociedade, transformando a jovem na mãe e educadora por excelência.

Discussions concerning belief revision, theorydevelopment, and ``creativity'' in philosophy andAI, reveal a growing interest in Peirce'sconcept of abduction. Peirce introducedabduction in an attempt to providetheoretical dignity and clarification to thedifficult problem of knowledge generation. Hewrote that ``An Abduction is Originary inrespect to being the only kind of argumentwhich starts a new idea'' (Peirce, CP 2.26).These discussions, however, led to considerabledebates about the precise way in which Peirce'sabduction can be used to explain knowledgegeneration (cf. Magnani, 1999; Hoffmann, 1999).The crucial question (...) is that of understandinghow we can get the new elements capableof enlarging our theories. Under thesecircumstances, it might be helpful to step outof the entanglement and reconsider the basis ofthe problem that originally triggered Peirce'sinterest in abduction. This will lead us toanother Peircean concept, that of ``diagrammaticreasoning,'' which I discuss here in the contextof his ``pragmatism.'' In this way, I hope toreach a better understanding of thecontribution of ``abduction'' to the knowledgegeneration process. (shrink)

In this book Tobias Hoffmann studies the medieval free will debate during its liveliest period, from the 1220s to the 1320s, and clarifies its background in Aristotle, Augustine, and earlier medieval thinkers. Among the wide range of authors he examines are not only well-known thinkers such as Thomas Aquinas, Duns Scotus, and William of Ockham, but also a number of authors who were just as important in their time and deserve to be rediscovered today. To shed further light on (...) their theories of free will, Hoffmann also explores their competing philosophical explanations of the fall of the angels, that is, the hypothesis of an evil choice made by rational beings under optimal psychological conditions. As he shows, this test case imposed limits on tracing free choices to cognition. His book provides a comprehensive account of a debate that was central to medieval philosophy and continues to occupy philosophers today. (shrink)

_The Arcades Project_, the monumental unfinished work of cultural criticism by Walter Benjamin, is the German philosopher’s effort to comprehend urban modernity through the 19th-century Parisian shopping arcade. _The Arcades: Contemporary Art and Walter Benjamin_ combines artworks with archival materials and poetic interventions to form an original, multifaceted response to this collagelike cultural text. Jens Hoffmann astutely pairs works by thirty-six well-known and emerging artists, including Lee Friedlander, Andreas Gursky, Pierre Huyghe, and Cindy Sherman, with the thirty-six “Convolutes,” or (...) themes, in Benjamin’s text. Bound into the main volume is a graphic novelette, from the imagination of Vito Manolo Roma, of Benjamin’s dream the night before he committed suicide while fleeing the Nazis. Scholarly essays by Hoffmann and Caroline A. Jones, texts selected by the poet Kenneth Goldsmith, reproductions of Benjamin’s handwritten notes, and a list of the main Paris arcades discussed by him round out this extraordinary publication. (shrink)

We study model theory of fields with actions of a fixed finite group scheme. We prove the existence and simplicity of a model companion of the theory of such actions, which generalizes our previous results about truncated iterative Hasse–Schmidt derivations [13] and about Galois actions [14]. As an application of our methods, we obtain a new model complete theory of actions of a finite group on fields of finite imperfection degree.

Metaphysical nihilism is the thesis that there could have been no concrete objects. Thomas Baldwin (1996) offers an argument for metaphysical nihilism. The premisses of the argument purport to provide a procedure of subtraction that can be iterated until we reach a world where no concrete objects exist. Gonzalo Rodriguez-Pereyra (1997) finds fault with Baldwin’s argument, modifies it, and claims to have proved metaphysical nihilism. My primary aim is to show that Rodriguez-Pereyra’s alleged proof rests on a false assumption. The (...) assumption is that, necessarily, if there are no concrete* objects (in the sense Rodriguez-Pereyra defines), then there are no concrete objects. My secondary aim, with which I begin, is to formulate and then strengthen a succinct version of the subtraction argument. (shrink)

To the woman, God said, “I will greatly multiply your pain in child bearing; in pain you shall bring forth children, yet your desire shall be for your husband, and he shall rule over you.”Genesis 3:16There is now a well-established body of literature documenting the pervasive inadequate treatment of pain in this country. There have also been allegations, and some data, supporting the notion that women are more likely than men to be undertreated or inappropriately diagnosed and treated for their (...) pain.One particularly troublesome study indicated that women are more likely to be given sedatives for their pain and men to be given pain medication. Speculation as to why this difference might exist has included the following: Women complain more than men; women are not accurate reporters of their pain; men are more stoic so that when they do complain of pain, “it's real”; and women are better able to tolerate pain or have better coping skills than men. (shrink)

Wicked problems—that is, problems that can be framed in a number of different ways, depending on who is looking at them—pose ethical challenges for professionals that have scarcely been recognized as such. Even though wicked problems are all around us, they are rarely addressed in education. A reason for this failure might be that wicked problems pose almost insurmountable challenges in educational settings. This contribution shows how students can learn to cope with wicked problems in problem-based learning projects that are (...) structured by the Reflect! platform. (shrink)

: During the "institutional revolution" between 1870 and 1910 almost two dozen physics institutes were newly erected in Germany. The design of these buildings was largely determined by sets of precautions against various sorts of disturbances. These undertakings were by no means unique. Recent historical studies have identified similar attempts in physics institutes outside Germany. But as yet, hardly a word has been wasted on the necessity of these precautionary measures. It seems to be self-explanatory that disturbances should be precluded (...) from scientific investigations. My paper criticizes this approach. The evidential nature of this assertion rests on the questionable assumption that disturbances are "external factors," which hinder physical research. I examine the 'architecture of disturbance' and show that it is the set of precautions itself which sometimes produces 'disturbing' effects. I then focus on particular sources of disturbance that were taken into account in the design of the buildings, and analyze the aporias that characterize the 'external' definition of disturbances. In conclusion, an alternative understanding of disturbances is offered. Following Michel Serres's concept of the parasite, I suggest that disturbances indicate the "being of relation" in physics research around 1900. From this point of view I finally sketch two novel features that governed the design of physics institutes after the turn of the century. (shrink)

Chemical structures are among the trademarks of our profession, as surely chemical as flasks, beakers and distillation columns. When someone sees one of us busily scribbling formulas or structures, he or she has no trouble identifying a chemist. Yet these familiar objects, which accompany our work from start to end, from the initial doodlings (Fig. I) to the final polished artwork in a publication (Fig. II), are deceptively simple. They raise interesting and difficult questions about representation. It is the intent (...) of this article to reflect upon molecular graphics. (shrink)

The possible-worlds analysis of propositions identifies a proposition with the set of possible worlds where it is true. This analysis has the hitherto unnoticed consequence that a proposition depends for its existence on the existence of every proposition that entails it. This peculiar consequence places the possible-worlds analysis in conflict with the conjunction of two compelling theses. One thesis is that a phrase of the form ‘the proposition that S’ is a rigid designator. The other thesis is that a proposition (...) which is directly about an object – a singular proposition – depends for its existence on the existence of the object. I defend these theses and conclude that the cost of the possible-worlds analysis is prohibitively high. (shrink)

Historically, biocentrists have ascribed interests to organisms via an account of function. One promising account of function for this purpose is the organizational or autopoietic account of function, according to which some entity x has a function of self-maintenance when the parts of x contribute to the goal of self-maintenance. In this paper, I will present the autopoietic account of interests and provide some reasons for thinking that this account is promising. I will also present a possible issue for the (...) biocentrist who uses the autopoietic account of function given the following two claims: what it means to be a biological “self” is ambiguous, and the autopoietic account of interests relies on a self boundary. I argue that the proponent of this account then needs to choose a definition of individual and explain why that definition is morally relevant. Otherwise, the proponent of the autopoietic account has not given an account of what constitutes a harm or a benefit for a biological individual, and there are good reasons to believe that this is a necessary component of any account of interests. (shrink)

We begin by presenting William of Ockham's various formulations of his principle of parsimony, Ockham's Razor. We then define a reaction mechanism and tell a personal story of how Ockham's Razor entered the study of one such mechanism. A small history of methodologies related to Ockham's Razor, least action and least motion, follows. This is all done in the context of the chemical (and scientific) community's almost unthinking acceptance of the principle as heuristically valuable. Which is not matched, to put (...) it mildly, by current philosophical attitudes toward Ockham's Razor. What ensues is a dialogue, pro and con. We first present a context for questioning, within chemistry, the fundamental assumption that underlies Ockham's Razor, namely that the world is simple. Then we argue that in more than one pragmatic way the Razor proves useful, without at all assuming a simple world. Ockham's Razor is an instruction in an operating manual, not a world view. Continuing the argument, we look at the multiplicity and continuity of concerted reaction mechanisms, and at principal component and Bayesian analysis (two ways in which Ockham's Razor is embedded into modern statistics). The dangers to the chemical imagination from a rigid adherence to an Ockham's Razor perspective, and the benefits of the use of this venerable and practical principle are given, we hope, their due. (shrink)

This paper intends to show that Aquinas gives a non-deterministic account of free decision. Angelic sin is the eminent test case: ex hypothesi, angels are supremely intelligent and not subject to ignorance, passions, or negatively disposing habits. Nothing predetermines their choice; rather it ultimately depends on their freedom alone. All angels acted based upon reasons, but why certain angels acted for an inadequate reason whereas others for an adequate reason cannot be fully explained. Thomas's action theory allows him to explain (...) angelic choice as contingent and selfdetermined. The salient features of this explanation are transferable to human free decision. (shrink)

This experiment investigated the use of positive and negative hypothesis and target tests by groups in an adaptation of the 2-4-6 Wason task. The experimental variables were range of rule (small vs large), amount of evidence (low vs high), and trial block (1 vs 2). The results were in accordance with Klayman and Ha's (1987) analysis of base rate probabilities of falsification and with additional theoretical considerations. Base rate probabilities were more descriptive of participants' behaviour in target than in hypothesis (...) tests, under low than under high amount of evidence, and at the beginning of the process than at its end. The percentage of positive tests was higher under small than large range of rule. More falsifications than verifications resulted from hypothesis tests than would be expected by a random process. When evidence is richly available, the relative importance of falsification seems to decrease. An analysis of the group compositions before and after group discussion by the PCD model (Crott, Werner, & Hoffmann, 1996) revealed that the normative weight was approximately twice as large as the informational. Groups produced fewer false answers than their members individually. (shrink)

A property is intrinsic iff individuals have it in virtue of how they themselves are, not in virtue of their relations to other individuals; a property is extrinsic iff it is not intrinsic. Being a cube and being an electron are intrinsic properties; being next to a cube, and being repelled by an electron are extrinsic properties. The debate about the distinction between intrinsic and extrinsic properties revolves around the following two questions: (1) Can the distinction be analysed in terms (...) of other, better understood notions, and if so, what should such an analysis should look like? (2) What are the general characteristics of the intrinsic/extrinsic distinction? I first describe several attempts to define the intrinsic/extrinsic distinction: the loneliness test proposed by Langton and Lewis, combinatorial accounts, and approaches based on the notion of grounding. I point out that any successful analysis of the intrinsic/extrinsic distinction invokes notions based on substantial metaphysical assumptions, such as the notions of grounding or natural property. I then discuss the general features of the intrinsic/extrinsic distinction and argue that the distinction is hyperintensional and vague. (shrink)

ZusammenfassungDie Neue Rechte betreibt seit 2000 eine umfangreiche Literaturpolitik. Aktionen im Literaturbetrieb, eigene Publikationen sowie ein expandierender Literaturjournalismus werden mit zunehmendem Geschick und Erfolg dazu genutzt, neurechte Ideologien im Kulturbetrieb zu verankern. Dies zeigte sich u.a. in der 2020 um die Schriftstellerin Monika Maron geführten Debatte, die der Aufsatz zum Ausgangspunkt nimmt, um die wichtigsten metapolitischen Strategien neurechter Literaturpolitik vorzustellen: eine Veränderung des Lektürekanons, eine politische Funktionalisierung von Ästhetik und ästhetischer Erziehung sowie literaturbetriebliche Aktionen. Abschließend wird am Streit um den (...) Debutroman von Simon Strauß diskutiert, wie sich angemessen auf neurechte Literaturpolitik reagieren lässt.The New Right is pursuing an extensive literary policy since 2000. Activities in the literary business, publications and an expanding literary journalism are used to implant new-right ideologies in the cultural establishment with increasing skill and success. This became apparent, among other things, in the 2020 debate surrounding the writer Monika Maron, which the essay takes as its starting point in order to present the most important meta-political strategies of new-right literary politics: a change in the reading canon, a political functionalization of aesthetics and aesthetic education, as well as activism in the literary business. Finally, the controversy surrounding the debut novel by Simon Strauß will be used to discuss how to react appropriately to new-right literary politics. (shrink)

The author presents Gernot Böhme’s median mode of being theory, which attempts to find an anthropological middle ground between the rational and the irrational, the spiritual and the corporeal and the active and passive in human experience. Böhme’s reflections on the median mode of being are normative in character and linked to the concept of “sovereign man,” which he strongly defends and whose main characteristics Hoffmann outlines in the first part of the essay. Among others, Hoffmann argues against (...) Böhme’s excessive emphasis on the controlling/restrictive functions of awareness at the cost of those functions which serve to protect and stimulate life, his non-distinction between the distance to a cognized object and its intellectual instrumentalisation, and his rather one-sided tendency to seek the sources of European rationalism in the Socra-tean tradition. (shrink)

Was meinen wir, wenn wir sagen, dass etwas ist oder existiert? Und in welchem Sinn lässt sich von Gott sagen, dass er sei, existiere oder wirklich sei? Die Frage nach der Wirklichkeit Gottes wird in der aktuellen Debatte tendenziell verdeckt durch die in der Nähe liegende, aber doch auch mit ihr nicht identische Frage nach der erkenntnistheoretischen Zugänglichkeit der Wirklichkeit Gottes. Beiträge aus verschiedenen Fächern und theoretischen Zugängen innerhalb der Theologie und der Philosophie leuchten dieses Forschungsfeld aus und machen es (...) unter anderem fruchtbar für die aktuelle Diskussion um das Gott-Welt-Verhältnis, für die die Frage nach dem Wirklichkeitsverständnis von erheblicher Bedeutung ist. (shrink)

This article gives a basic account of Aquinas’s theory of “synderesis” and conscience. Aquinas understands synderesis as an infallible moral awareness and conscience as the fallible judgment that applies a general moral conviction to a concrete case. The article also compares Aquinas’s and his contemporaries’ theories of whether erring conscience is morally binding, that is, whether to act in accord with erring conscience or against erring conscience is sinful.

Had more philosophers of science come from chemistry, their thinking would have been different. I begin by looking at a typical chemical paper, in which making something is the leitmotif, and conjecture/refutation is pretty much irrelevant. What in fact might have been, might be, different? The realism of chemists is reinforced by their remarkable ability to transform matter; they buy into reductionism where it serves them, but make no real use of it. Incommensurability is taken without a blink, and actually (...) serves. The preeminence of synthesis in chemistry could have led philosophers of science to take more seriously questions of aesthetics within science, and to find a place in aesthetics for utility. The necessary motion twixt macroscopic and microscopic views of matter in modern chemistry leads to the coexistence of symbolic and iconic representations. And in another way to the deliberate, creative violation of categories. (shrink)

A key challenge for probabilistic causal models is to distinguish non-causal probabilistic dependencies from true causal relations. To accomplish this task, causal models are usually required to satisfy several constraints. Two prominent constraints are the causal Markov condition and the faithfulness condition. However, other constraints are also needed. One of these additional constraints is the causal sufficiency condition, which states that models must not omit any direct common causes of the variables they contain. In this paper, I argue that the (...) causal sufficiency condition is problematic: (1) it is incompatible with the requirement that the variables in a model must not stand in non-causal necessary dependence relations, such as mathematical or conceptual relations, or relations described in terms of supervenience or grounding, (2) it presupposes more causal knowledge as primitive than is actually needed to create adequate causal models, and (3) if models are only required to be causally sufficient, they cannot deal with cases where variables are probabilistically related by accident, such as Sober’s example of the relationship between bread prices in England and the sea level in Venice. I show that these problems can be avoided if causal models are required to be monotonic in the following sense: the causal relations occurring in a model M would not disappear if further variables were added to M. I give a definition of this monotonicity condition and conclude that causal models should be required to be monotonic rather than causally sufficient. (shrink)

Most of the epistemological debate on disagreement tries to develop standards that describe which actions or beliefs would be rational under specific circumstances in a controversy. To build things on a firm foundation, much work starts from certain idealizations—for example the assumption that parties in a disagreement share all the evidence that is relevant and are equal with regard to their abilities and dispositions. This contribution, by contrast, focuses on a different question and takes a different route. The question is: (...) What should people actually do who find themselves in deep disagreement with others? And instead of building theory on some “firm foundation,” the paper starts from a specific goal—building consensus by creating new proposals—and asks, first, which actions are suitable to achieve this goal and, second, what are the epistemic conditions of these actions. With regard to the latter, the paper focuses on what has been called framing and reframing in conflict research, and argues that both metaphors need and deserve a suitable epistemological conceptualization. (shrink)